Earth's Energy Budget (Week 3) - Post 1

Earth's Energy Budget- Notes

Overview
Section 3 will follow energy through the climate system. There are essentially three main factors to consider: incoming energy from the Sun, reflection of solar energy, and the greenhouse effect. We’ll have a look at Earth’s energy budget, which includes these big three plus some additional processes, and we’ll have a look at balances and imbalances in energy flows. Understanding solar energy, reflection, and the greenhouse effect are crucial for designing effective mitigation efforts.

3.1 Notes
The Electromagnetic Spectrum


The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies. This frequency range is divided into separate bands, and the electromagnetic waves within each frequency band are called by different names. The electromagnetic waves in each of these bands have different characteristics, such as how they are produced, how they interact with matter, and their practical applications.

Ionizing Radiation- Gamma rays, X-rays, and high Ultraviolet light: Their photons have enough energy to ionize (ionization is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons to form ions atoms) causing chemical reactions. Exposure to these rays can be a health hazard, causing radiation sickness, DNA damage and cancer.

Nonionizing Radiation- Visible light wavelengths and lower: they cannot cause the effects of ionizing radiation.

Spectroscopy- A technique that is used to physically separate waves of different frequencies, producing a spectrum showing the constituent frequencies. Its used to study the interactions of electromagnetic waves with matter.
Range of Spectrum
Wavelength ( λ )- The spatial period of the wave, or the distance over which the wave’s shape repeats. It’s usually determined by considering the distance between consecutive corresponding points of the same phase (such as crests or troughs).

Frequency ( f )- The number of occurrences of a repeating event per unit of time.

Photon Energy ( E )- The energy carried by a single photon. Photon energy is solely a function of the photon’s wavelength. Other factors, such as the intensity of the radiation, do not affect photon energy.

Wavelength, Frequency, and Photon Energy Relationships:
+Wavelength and Frequency are inversely proportional: waves with higher frequencies have shorter wavelengths, and lower frequencies have longer wavelengths. So, gamma rays on the far end of the EM spectrum (wavelengths) have tiny wavelengths, while radio waves on the opposite end of the spectrum have huge wavelengths.
+Photon Energy and Frequency are directly proportional, so gamma ray photons have the highest energy, while radio wave photons have very low energy. The amount of photon energy is also inversely proportional to the wavelength.  

These relationships are illustrated within the equations below:
f= c/ λ             f= E/h            E= h*c/ λ
c = 299792458 m/s = The speed of light in a vacuum
h = 6.62606896(33)×10−34 J·s = 4.13566733(10)×10−15 eV·s = Planck’s Constant  

Types of Radiation
Bands of The EM Spectrum Climate Science Concerns:
Infrared Radiation-
The infrared part of the electromagnetic spectrum covers the range from roughly 300 GHz to 400 THz (1 mm - 750 nm). It can be divided into three parts:
Far-infrared- from 300 GHz to 30 THz (1 mm – 10 μm). This radiation is typically absorbed by so-called rotational modes in gas-phase molecules, by molecular motions in liquids, and by phonons in solids. The water in Earth's atmosphere absorbs so strongly in this range that it renders the atmosphere in effect opaque. However, there are certain wavelength ranges ("windows") within the opaque range that allow partial transmission and can be used for astronomy.
Mid-infrared- from 30 to 120 THz (10–2.5 μm). Hot objects (black-body radiators) can radiate strongly in this range, and human skin at normal body temperature radiates strongly at the lower end of this region. This radiation is absorbed by molecular vibrations, where the different atoms in a molecule vibrate around their equilibrium positions.
Near-infrared- from 120 to 400 THz (2,500–750 nm). Physical processes that are relevant for this range are similar to those for visible light. The highest frequencies in this region can be detected directly by some types of photographic film, and by many types of solid state image sensors for infrared photography and videography.

Visible Radiation-
Above infrared in frequency comes visible light. The Sun emits its peak power in the visible region, although integrating the entire emission power spectrum through all wavelengths shows that the Sun emits slightly more infrared than visible light. By definition, visible light is the part of the EM spectrum the human eye is the most sensitive to… The light that excites the human visual system is a very small portion of the electromagnetic spectrum. A rainbow shows the optical (visible) part of the electromagnetic spectrum; infrared (if it could be seen) would be located just beyond the red side of the rainbow with ultraviolet appearing just beyond the violet end… Electromagnetic radiation with a wavelength between 380 nm and 760 nm (400–790 terahertz) is detected by the human eye and perceived as visible light. Other wavelengths, especially near infrared (longer than 760 nm) and ultraviolet (shorter than 380 nm) are also sometimes referred to as light, especially when the visibility to humans is not relevant.

Ultraviolet Radiation-
UV is the longest wavelength radiation whose photons are energetic enough to ionize atoms, separating electrons from them, and thus causing chemical reactions. Short wavelength UV and the shorter wavelength radiation above it (X-rays and gamma rays) are called ionizing radiation, and exposure to them can damage living tissue, making them a health hazard. UV can also cause many substances to glow with visible light; this is called fluorescence… At the middle range of UV, UV rays cannot ionize but can break chemical bonds, making molecules unusually reactive. Sunburn, for example, is caused by the disruptive effects of middle range UV radiation on skin cells, which is the main cause of skin cancer… The Sun emits significant UV radiation (about 10% of its total power), including extremely short wavelength UV that could potentially destroy most life on land (ocean water would provide some protection for life there). However, most of the Sun's damaging UV wavelengths are absorbed by the atmosphere before they reach the surface.

Video Lesson- Energy from the Earth and Sun
The Sun is really hot, because its hot, it gives off lots of energy per second, per square meter—much, much more than the Earth gives off. Also, because its hot, the sun gives off radiation at visible wavelengths, and the Earth, because its cooler, gives off radiation at infrared wavelengths. — The primary reason to spend time on these relationships is so we can use them, when we have to look the different types of energy transferring around within Earth’s climate system. 

Key Points-
+The Sun gives off shortwave (High photon energy) radiation with a peak wavelength in the visible part of the electromagnetic spectrum.
+The Earth gives off long wave (Low photon energy) radiation with a peak wavelength in the infrared part of the electromagnetic spectrum.
+The general relationships are that
            -Hotter objects emit more radiation than cooler objects
            -Hotter objects emit radiation at shorter wavelengths than cooler objects.
+Coming up: These differences between radiation from the Sun and radiation from the Earth are crucial to understanding the greenhouse effect. 




3.2 Notes

Ins and Outs of Earth’s Energy Budget:
Here we’ll examine the main processes by which energy flows in, out, and within Earth’s climate system. We’ll spend some time with an iconic figure showing Earth’s annual energy budget, and examine it from a stock and flow perspective.
Learning Goals:
By the end of this section, you will be able to:
+Describe how incoming and outgoing electromagnetic radiation interacts with Earth’s surface and its atmosphere.
+Balance energy budgets for the top of the atmosphere, the atmosphere, and Earth’s surface.
+Predict how changes in incoming solar energy, greenhouse gases, and albedo will affect a planet’s mean surface temperature.
Video Lesson
*Fundamentally, any mitigation actions we choose to take have to align with the energy flows talked about below.
Key Points
+Shortwave (Hot) radiation from the Sun is the ultimate source of energy for Earth’s climate system.
+About 30% of incoming solar radiation gets reflected directly back to space.
+Earth absorbs energy from two sources: incoming solar energy and energy re-emitted back toward the Earth by greenhouse gasses.
+Earth therefore heats up to a temperature at which it can radiate enough energy such that its energy outflow will balance its energy inflow.
+The planet is currently out of balance, with inflow exceeding outflow
+Earth’s temperature will rise until inflow and outflow are back in balance. (Amplifying Feedback Look)
Readings

Sunspots
Sunspots are darker, cooler areas on the surface of the sun in a region called the photosphere. The photosphere has a temperature of 5,800 degrees Kelvin. Sunspots have temperatures of about 3,800 degrees K. They look dark only in comparison with the brighter and hotter regions of the photosphere around them.
They are caused by interactions with the Sun's magnetic field which are not fully understood. But a sunspot is somewhat like the cap on a soda bottle: shake it up, and you can generate a big eruption. Sunspots occur over regions of intense magnetic activity, and when that energy is released, solar flares and big storms called coronal mass ejections erupt from sunspots.

(Pages 11-12)
How do we know the current warming trend isn’t caused by the sun?
Because the Sun’s output has a strong influence on Earth’s temperature, scientists have examined records of solar activity to determine if changes in solar output might be responsible for the observed global warming trend… The most direct measurements of solar output are satellite readings, which have been available since 1979. These satellite records show that the Sun’s output has not shown a net increase during the past 30 years and thus cannot be responsible for the warming during that period.
Further evidence that current warming is not a result of solar changes can be found in the temperature trends in the different layers of the atmosphere. These data come from two sources: weather balloons, which have been launched twice daily from hundreds of sites worldwide since the late 1950s, and satellites, which have monitored the temperature of different layers of the atmosphere since the late 1970s. Both datasets have been heavily scrutinized, and both show a warming trend in the lower layer of the atmosphere (the troposphere) and a cooling trend in the upper layer (the stratosphere). This is exactly the vertical pattern of temperature changes expected from increased greenhouse gases, which trap energy closer to the Earth’s surface.




3.3 Notes
About 30% of the solar energy that arrives at our planet gets reflected back to space nearly immediately. Here we’ll look at some of the important reflective materials in Earth’s climate system. Reflectivity is involved in some important feedback loops in the climate system, and some mitigation strategies involve deliberately influencing reflectivity.
Learning Goals
By the end of this section, you will be able to: 
+Explain how reflection fits into Earth’s overall energy budget.
+Rank different surfaces based on their reflectivity (e.g. deserts, forests, clouds, ice, ocean water etc.).
+Predict how particular changes in the reflective properties of Earth’s surface or atmosphere would likely affect Earth’s temperature.
+Construct feedback loops involving reflectivity.

Readings
Albedo is a measure of how reflective a surface is. It is a measure of the proportion of the incoming solar radiation that is reflected by the surface back into the atmosphere and space… The more reflective a surface is the higher the albedo value. Very white surfaces, such as fresh snow, reflect a very high fraction of incoming radiation back to space. Darker surfaces such as water, forests or asphalt have a much lower albedo and more of the sun's energy is absorbed… Much of the planet each day is covered by cloud which will have a different albedo to the surface. White clouds reflect more sunlight than water and darker land surfaces. Tiny particles in our atmosphere such as dust, smoke and pollen (known as 'aerosols') also affect the overall reflection of incoming solar radiation.
* In a weather and climate context we often refer to the Earth's surface albedo for the reflectivity of the surface, and the planetary albedo for the reflectivity of the Earth when viewed from space, including the effect of the atmosphere, clouds and aerosols.
Albedo is a very important factor in both weather and climate. The amount of sunlight that is absorbed or reflected is a driving force of our weather… Changes in the albedo of the Earth's surface, caused by changes in land surface type affect the Earth's 'energy budget'. If less energy is reflected, then there will be a warming effect. This can lead to feedbacks, as if there is extensive snow melt, more energy will be absorbed, leading to more surface heating and more snow melt. On a large scale this has implications for our climate.
Tutorial
How to calculate the overall albedo for a region?
Various parts of each region all have a different albedo value. The total albedo value is the weighted averages of the albedo values for each contributing part.
(Depending on the choppiness of the ocean, it reflects between 5% and 30% of the heat energy it receives; so, the general albedo value for the ocean is 0.10. All albedo values are expressed between 0 and 1.)

( (area x albedo) + (area x albedo) + (area x albedo) )/ total area = Regional Albedo

*Note- The albedo is the amount of the sun’s energy reflected away from the surface; an important aspect is that is changes with the angle that the sun’s rays strike the surface. Using the ocean as an example, when the sun is high in the sky, there is less reflection and hence reduced albedo (about 0.10), but when the sun is low on the horizon, more of its energy is reflected by the water’s surface and albedo is greater (up to 0.33).

Video Lesson- Reflection of Incoming Solar Radiation
-Earth’s reflectivity can influence and be influenced by other parts of the climate system.  -Amplifying system- the response helps push the system in the same direction as the original perturbation 
-Reflectivity issues in the climate- just like in other parts of the climate system, it’s changes in the stocks of things that can influence energy flows. If the stocks of clouds, or reflective particles, or forests, or ocean water changes, the amount of energy reflected directly back to space will also change and will alter earth’s energy balance.
Key Points
+Changes in Earth’s surface toward more reflective materials promote cooling; changes toward less reflective materials promote warming. 
+On Earth’s surface, changes in vegetation cover and land use can alter reflectivity.
+In the atmosphere, changes in cloud cover and the stock of reflective aerosols can change Earth’s overall reflectivity.
+Reflection is involved in important feedback loops in the climate system.
+Feedbacks involving clouds are not well-constrained, but recent research suggests that cloud feedback in a warming world are likely to be net amplifying.  

                                                                               Reading
-Aerosols: A suspension of fine solid particles or liquid droplets in a gas 
-Stratospheric sulfur aerosols are sulfur-rich particles which exist in the stratosphere region of the Earth's atmosphere. The layer of the atmosphere in which they exist is known as the Junge layer, or simply the stratospheric aerosol layer.
- When present in high levels, e.g. after a strong volcanic eruption such as Mount Pinatubo, they produce a cooling effect, by reflecting sunlight, and by modifying clouds as they fall out of the stratosphere. This cooling may persist for a few years before the particles fall out.
- The relative influence of volcanoes on the Junge layer varies considerably according to the number and size of eruptions in any given time period, and also of quantities of sulfur compounds released. Only stratovolcanoes containing primarily granitic rocks are responsible for these fluxes, as basaltic rock erupted in shield volcanoes doesn't result in plumes which reach the stratosphere.
- The IPCC AR4 says explosive volcanic events are episodic, but the stratospheric aerosols resulting from them yield substantial transitory perturbations to the radiative energy balance of the planet, with both shortwave and longwave effects sensitive to the microphysical characteristics of the aerosols.
-Understanding of these aerosols comes in large part from the study of volcanic eruptions, notably Mount Pinatubo in the Philippines The formation of the aerosols and their effects on the atmosphere can also be studied in the lab. Samples of actual particles can be recovered from the stratosphere using balloons or aircraft. Computer models can be used to understand the behavior of aerosol particles and are particularly useful in modelling their effect on global climate.
-General Process: It has been established that emission of precursor gases for sulfur aerosols is the principal mechanism by which volcanoes cause episodic global cooling. The Intergovernmental Panel on Climate Change AR4 regards stratospheric sulfate aerosols as having a low level of scientific understanding. The aerosol particles form a whitish haze in the sky. This creates a global dimming effect, where less of the sun's radiation is able to reach the surface of the Earth. This leads to a global cooling effect. In essence, they act as the reverse of a greenhouse gas, which tends to allow visible light from the sun through, whilst blocking infrared light emitted from the Earth's surface and its atmosphere. The particles also radiate infrared energy directly, as they lose heat into space.
- Creating stratospheric sulfur aerosols deliberately is a proposed geoengineering technique which offers a possible solution to some of the problems caused by global warming. However, this will not be without side effects and it has been suggested that the cure may be worse than the disease. 



3.4 Notes

The greenhouse effect is the reason planet Earth’s average surface temperature is above freezing. Particular gases (greenhouse gases) in the atmosphere have chemical structures that allow them to absorb, then re-emit infrared radiation coming from Earth’s surface. Here we’ll examine the basics of greenhouse gases and how the greenhouse effect works, which helps us understand why human additions of greenhouse gases to the atmosphere cause warming. Influencing flows of greenhouse gases to and from the atmosphere are another place to look for mitigation options.

-Learning Goals-

By the end of this section, you will be able to:
+Identify greenhouse gases; identify non-greenhouse gas air molecules.
+Contrast the molecular structure of greenhouse gases and non-greenhouse gases.
+Describe how greenhouse gases themselves absorb and emit radiation, including what kinds of radiation (shortwave or longwave).
+Explain how the greenhouse effect warms Earth in terms of energy flows.
+Describe feedbacks involving the greenhouse effect.


Reading

-The atmosphere of Earth is the layer of gases, commonly known as air, that surrounds the planet Earth and is retained by Earth's gravity.
- By volume, dry air contains 78.09% nitrogen, 20.95% oxygen,[2] 0.93% argon, 0.04% carbon dioxide, and small amounts of other gases. Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere.
-The three major constituents of air, and therefore of Earth's atmosphere, are nitrogen, oxygen, and argon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. (The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by volume in the coldest portions of the atmosphere to as much as 5% by volume in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor))
-Air content and atmospheric pressure vary at different layers, and air suitable for use in photosynthesis by terrestrial plants and breathing of terrestrial animals is found only in Earth's troposphere and in artificial atmospheres.
-The remaining gases are often referred to as trace gases,[6] among which are the greenhouse gases, principally carbon dioxide, methane, nitrous oxide, and ozone. Filtered air includes trace amounts of many other chemical compounds. Many substances of natural origin may be present in locally and seasonally variable small amounts as aerosols in an unfiltered air sample


 Major constituents of dry air, by volume
                 Gas
         Volume
Name
Formula
in ppmv
in %
N2
780,840
78.084
O2
209,460
20.946
Ar
9,340
0.9340
CO2
400
0.04
Ne
18.18
0.001818
He
5.24
0.000524
CH4
1.79
0.000179
       Not included in above dry atmosphere:
H2O
10–50,000
0.001%–5%
(PPMV- Parts Per Million by Volume)










Computer Simulation Activity

In this posting, we consider the interaction between air molecules, including Nitrogen (N2), Oxygen (O2), Water Vapor (H2O) and Carbon Dioxide (CO2), with Photons of various wavelengths. This may help us visualize how energy, in the form of Photons radiated by the Sun and the Surface of the Earth, is absorbed and re-emited by Atmospheric molecules.

Video Lesson

-Greenhouse gasses are those that absorb and re-emit infrared radiation coming from earth’s surface
+Greenhouse gases are those that can absorb and re-emit infrared radiation in the wavelength range of energy emitted by Earth’s surface.
+The major constituents in our atmosphere, N2 and 02, are NOT greenhouse gasses (because of chemical structure)


+When greenhouse gases emit infrared radiation, they emit it in random directions.

-Some goes back toward Earth’s surface and gets re-absorbed
-Some goes toward space
-Some goes to another greenhouse gas molecule which repeats the absorption and re-emission and sends the energy in another direction.
+Greenhouse gases slow the passage of infrared energy from Earth’s surface to space, warming the planet.
Reading
-AIRS is the first instrument to distinguish differences in the amount of water vapor at all altitudes within the troposphere. Using data from AIRS, the team observed how atmospheric water vapor reacted to shifts in surface temperatures between 2003 and 2008. By determining how humidity changed with surface temperature, the team could compute the average global strength of the water vapor feedback.
-“This new data set shows that as surface temperature increases, so does atmospheric humidity,” Dessler said. “Dumping greenhouse gases into the atmosphere makes the atmosphere more humid. And since water vapor is itself a greenhouse gas, the increase in humidity amplifies the warming from carbon dioxide."
-Specifically, the team found that if Earth warms 1.8 degrees Fahrenheit, the associated increase in water vapor will trap an extra 2 Watts of energy per square meter (about 11 square feet).
-"That number may not sound like much but add up all of that energy over the entire Earth surface and you find that water vapor is trapping a lot of energy," Dessler said. "We now think the water vapor feedback is extraordinarily strong, capable of doubling the warming due to carbon dioxide alone."
-Because the new precise observations agree with existing assessments of water vapor's impact, researchers are more confident than ever in model predictions that Earth's leading greenhouse gas will contribute to a temperature rise of a few degrees by the end of the century.


-Climate models (Computer simulations of the climate system) are designed to simulate the responses and interactions of the oceans and atmosphere, and to account for changes to the land surface, both natural and human-induced. They comply with fundamental laws of physics—conservation of energy, mass, and momentum—and account for dozens of factors that influence Earth’s climate.

-Changes to one part of the climate system can cause additional changes to the way the planet absorbs or reflects energy. These secondary changes are called climate feedbacks, and they could more than double the amount of warming caused by carbon dioxide alone. The primary feedbacks are due to snow and ice, water vapor, clouds, and the carbon cycle.

-Water Vapor: The largest feedback is water vapor. Water vapor is a strong greenhouse gas. In fact, because of its abundance in the atmosphere, water vapor causes about two-thirds of greenhouse warming, a key factor in keeping temperatures in the habitable range on Earth… As temperatures warm, the atmosphere becomes capable of containing more water vapor, and so water vapor concentrations go up to regain equilibrium. Will that trend hold as temperatures continue to warm?... The amount of water vapor that enters the atmosphere ultimately determines how much additional warming will occur due to the water vapor feedback. The atmosphere responds quickly to the water vapor feedback….The amount of water vapor that enters the atmosphere ultimately determines how much additional warming will occur due to the water vapor feedback. The atmosphere responds quickly to the water vapor feedback… If this trend continues, and many models say that it will, water vapor has the capacity to double the warming caused by carbon dioxide alone.

-Clouds: Scientists aren’t entirely sure where and to what degree clouds will end up amplifying or moderating warming, but most climate models predict a slight overall positive feedback or amplification of warming due to a reduction in low cloud cover.

-The Carbon Cycle: For now, primarily ocean water, and to some extent ecosystems on land, are taking up about half of our fossil fuel and biomass burning emissions. This behavior slows global warming by decreasing the rate of atmospheric carbon dioxide increase, but that trend may not continue. Warmer ocean waters will hold less dissolved carbon, leaving more in the atmosphere… The impact of climate change on the land carbon cycle is extremely complex, but on balance, land carbon sinks will become less efficient as plants reach saturation, where they can no longer take up additional carbon dioxide, and other limitations on growth occur, and as land starts to add more carbon to the atmosphere from warming soil, fires, and insect infestations. This will result in a faster increase in atmospheric carbon dioxide and more rapid global warming. In some climate models, carbon cycle feedbacks from both land and ocean add more than a degree Celsius to global temperatures by 2100.

-Emission Scenarios: Scientists predict the range of likely temperature increase by running many possible future scenarios through climate models… the most significant source of uncertainty in these predictions is that scientists don’t know what choices people will make to control greenhouse gas emissions. The higher estimates are made on the assumption that the entire world will continue using more and more fossil fuel per capita, a scenario scientists’ call “business-as-usual.” More modest estimates come from scenarios in which environmentally friendly technologies such as fuel cells, solar panels, and wind energy replace much of today’s fossil fuel combustion. These considerations mean that people won’t immediately see the impact of reduced greenhouse gas emissions. Even if greenhouse gas concentrations stabilized today, the planet would continue to warm by about 0.6°C over the next century because of greenhouses gases already in the atmosphere.


 



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